[54] Four-electron reduction of CO₂: from formaldehyde and acetal synthesis to complex transformations

 

Sarah Desmons, Julien Bonin,* Marc Robert,* and Sébastien Bontemps*

Chem. Sci. 2024, Advance Article, Abstract

 

 

 

 

[53] Borohydride Compounds Catalyze the Selective 4e^– Reduction of CO₂ with 9-BBN

Carlos Jarava-Barrera, Sarah Desmons, Dan Zhang, Laure Vendier, Qingli Xu, Nana Ma,* Sébastien Bontemps*

J. Org. Chem. 2024, ASAP Abstract

 

 

 

 

 

 

 

[52] Reaction of a Bulky β-Diketiminato Magnesium Hydride with CO₂ Yielding a Polynuclear Magnesium Cage Compound

Wimonsiri Huadsai, Laure Vendier, Matthias Westerhausen,* Sébastien Bontemps*

ZAAC 2024, e202400070, Abstract

 

 

 

[51] Single electron reduction of NHC-CO₂-borane compounds

Agustín Morales, Caroline Gonçalves, Alix Sournia-Saquet, Laure Vendier, Agustí Lledós,* Olivier Baslé,* Sébastien Bontemps*

Chem. Sci. 2024, 15, 3165 – 3173, Abstract

 

 

[50] Stoichiometric and Catalytic Reduction of Carbon Dioxide by a Sterically Encumbered Amidinato Magnesium Hydride

 

Wimonsiri Huadsai, Laure Vendier, Helmar Görls, Lionel Magna, Sébastien Bontemps* and Matthias Westerhausen*

 

Eur. J. Inorg. Chem., 2024, accepted

 

 

 

[49] A Photocatalytic Approach for the Synthesis of L-Shape Bicyclic NHC Ligands

Tanakorn Kittikool, Kunita Phakdeeyothin, Agustín Morales, Cécile Barthes, Dr. Laure Vendier, Prof. Sirilata Yotphan, Dr. Sébastien Bontemps, Stéphanie Bastin, Prof. Agustí Lledós, Dr. Olivier Baslé, Dr. Vincent César

  

ChemistryEurope 2024, 2, e202300083, Abstract

 

 

 

[48] Doubly Base-Stabilized Diborane(4) and Borato-Boronium Species and Their Chemistry with Chalcogens

 

Asif Ahmad, Sourav Gayen, Shivankan Mishra, Zeenat Afsan, Sébastien Bontemps, and Sundargopal Ghosh*

 

Inorg. Chem., 2024, 63, 3376–3382, Abstract

 

 

[47] Synthesis and coordination of a bisphosphine-[NHC-borane] compound: a ligand framework for bimetallic structure featuring a boron-bridging moiety

Aurèle Camy, Laure Vendier, Christian Bijani, Israel Fernández* and Sébastien Bontemps*

Inorg. Chem., 2023, 62, 9035-9043, Abstract

 

 

 

[46] Alkaline Earth-Catalyzed CO₂ Hydroboration into Acetal Derivatives Leading to C-S Bond Formation.

 

Wimonsiri Huadsai, Matthias Westerhausen,* Sébastien Bontemps*

 

Organometallics, 2023, 42, 2921-2926, Abstract

 

 

 

 

[45] CO₂ Hydroboration: Impact of the Boryl Moieties on the Reactivity of Four Bis(boryl)acetal Compounds toward 2,6-Diisopropylaniline

 

Sarah Desmons, Yu Zhou, Dan Zhang, Carlos Jarava-Barrera, Anaïs Coffinet, Antoine Simonneau, Laure Vendier, Gen Luo,* Sébastien Bontemps*

 

 

Eur. J. Org. Chem., 2023, e202300525, Abstract

 

 

 

[44] Combined B-H and Si-H bond activations at ruthenium

Ramaraj Ayyappan, Koushik Saha, Urminder Kaur, Sourav Gayen, Laure Vendier, Sylviane Sabo-Etienne, Sundargopal Ghosh,* Sébastien Bontemps*

 

Organometallics, 2023, 42, 752-7561, Abstract

 

 

 

[43] Group IV Complexes with Sterically Congested N-Aryl-adamantylcarbamidate Ligands

Bahareh Rezaei Kheirkhah, Wimonsiri Huadsai, Phil Liebing, Sébastien Bontemps,* Matthias Westerhausen*

 

Organometallics, 2023, 42, 2304-2311, Abstract

 

 

 

[42] A masked form of an O-borylated Breslow intermediate for the diastereoselective FLP-type activation of aldehydes

Angelica Mejia Fajardo, Nicolas Queyriaux, Aurèle Camy, Laure Vendier, Mary Grellier, Iker del Rosal, Laurent Maron,* Sébastien Bontemps*

 

Chem. Eur. J., 2022, e202104122, Abstract

 

 

 

[41] Synthesis and characterisation of a very low-coordinate diferrous [2Fe-2S](0) unit

Christian Schneider, Sophie Gross, Serhiy J. Demeshko, Sébastien Bontemps, Franc Meyer, C. Gunnar Werncke*

Chem. Commun., 2021, 57, 10751-10754, Abstract

 

 

[40] Enantioselective Reductive Oligomerization of Carbon Dioxide into L‑Erythrulose via a Chemoenzymatic Catalysis

Sarah Desmons,* Katie Grayson-Steel, Nelson Nuñez-Dallos, Laure Vendier, John Hurtado, Pere Clapés,
Régis Fauré, Claire Dumon, and Sébastien Bontemps*

J. Am. Chem. Soc.  2021, 143, 39, 16274-16283, Abstract

 

 

 

[39] Selective Reductive Dimerization of CO₂ into Glycolaldehyde

Dan Zhang, Carlos Jarava-Barrera, and Sébastien Bontemps*

ACS Catal. 2021, 11, 4568−4575, Abstract

 

[38] Impact of the Alkali Metal on the Structural and Dynamic Properties of the Anionic Pentahydride Ruthenium Complexes [M(THF)_x][RuH₅(PCy₃)₂] (M = Li, Na, K)

Ramaraj Ayyappan, Koushik Saha, Mary Grellier, Eric Clot, Laure Vendier, Sundargopal Ghosh, Sylviane Sabo-Etienne*, and Sébastien Bontemps*

Organometallics 2021, 40, 17, 3024–3032, Abstract

 

 

 

[37] Borane-catalysed dinitrogen borylation by 1,3-B–H bond addition

 Anaïs Coffinet, Dan Zhang, Laure Vendier, Sébastien Bontemps and Antoine Simonneau*

Dalton Trans. 2021, 50, 5582-5589, Abstract

 

 

 

[36] Synthesis and reactivity of phosphine borohydride compounds

R. Ayyappan, Y. Coppel, L. Vendier, S. Ghosh, S. Sabo-Etienne, S. Bontemps*

Chem. Comm. 2021, 57, 375 - 378, Abstract

 

 

[35] Quasilinear 3d-Metal(I) Complexes [KM(N(Dipp)SiR₃)₂] (M = Cr − Co) – Structural Diversity, Solution Behaviour and Reactivity

R. Weller, I. Müller, C. Duhayon, S. Sabo-Etienne, S. Bontemps, C. G. Werncke,*

Dalton Trans. 2021, 50, 4890-4903, Abstract

 

[34] Cooperative B–H and Si–H Bond Activations by κ²-N,S-Chelated Ruthenium Borate Complexes

M. Zafar, R. Ramalakshmi, A. Ahmad, P. K. S. Antharjanam, S. Bontemps, S. Sabo-Etienne, S. Ghosh^*

Inorg. Chem.  2021, 60, 2, 1183–1194 Abstract

 

 

[33] NH₃ formation from N₂ and H₂ mediated by molecular tri-iron complexes

M. Reiners, D. Baabe, K. Münster, M.-K. Zaretzke, M. Freytag, P. G. Jones, Y. Coppel, S. Bontemps, I. del Rosal, L. Maron, M. D. Walter^*

Nat. Chem. 2020, 12, 740–746 Abstract

 

 

[32] Formaldehyde as a Promising C₁ Source: the Instrumental Role of Biocatalysis for Stereocontrolled Reactions

S. Desmons, R. Fauré,* S. Bontemps*

ACS Catal.  2019, 9, 9575−9588, Abstract 

 

 

[31] Versatile CO₂ Transformations into Complex Products: a One-pot Two-step Strategy

S. Desmons, D. Zhang, A. Mejia Fajardo, S. Bontemps*

J. Vis. Exp. 2019 (153), e60348, Abstract

 

 

[30] Reductive CO₂ homocoupling: synthesis of a borylated C₃ carbohydrate

A. Bethegnies, Y. Escudié, N. Nunez-Dallos, L. Vendier, J. Hurtado, I. Del Rosal, L. Maron , S. Bontemps*

Chem. Cat. Chem. 2019, 11, 760-765, Abstract

 

 

[29] C-Halide bond cleavage by a two-coordinate iron(I) complex

C. G. Werncke,* J. Pfeiffer, I. Müller, L. Vendier, S. Sabo-Etienne, S. Bontemps

Dalton Trans., 2019, 48, 1757-1765, Abstract

 

 

[28] Ortho-Pheny dialkylphosphonium sulfonate compounds: two rotamers in equilibrium

E. Martin-Mothes, E. Puig, L. Vendier, C. Bijani, M. Grellier, S. Bontemps*

Dalton Trans. 2018, 47, 10139-10146, Abstract

 

[27] Crystal Structure and Magnetic Characterization of Three-Coordinate [M{N(SiMe3)2}2(PCyp3)] Complexes with M = MnII, FeII, and CoII (Cyp = Cyclopentyl)

C. G. Werncke, L. Vendier, S. Sabo-Etienne, J.-P. Sutter, C. Pichon,* S. Bontemps*

Eur. J. Inorg. Chem. 2017, 2017, 1041-1406, Abstract

 

 

[26] Ising-type Magnetic Anisotropy and Slow Relaxation of the Magnetization in Four-Coordinate Amido-Pyridine FeII Complexes

C. Gunnar Werncke, Mohammed-Amine Bouammali, Julie Baumard, Nicolas Suaud, Cyril Martins,  Nathalie Guihéry,* Laure Vendier, Jianxia Zheng, Jean-Baptiste Sortais, Christophe Darcel,  Sylviane Sabo-Etienne, Jean-Pascal Sutter, Sébastien Bontemps* and Céline Pichon*

Inorg. Chem. 2016, 55, 21, 10968-10977, Abstract

 

 

[25] Homoleptic Two-Coordinate Silylamido Complexes of Chromium(I), Manganese(I), and Cobalt(I)

C. Gunnar Werncke, Elizaveta Suturina, Philip C. Bunting, Laure Vendier, Jeffrey R. Long, Mihail Atanasov, Frank Neese,* Sylviane Sabo-Etienne and Sébastien Bontemps*

Chem., Eur. J. 2016, 22, 1668-1674. Abstract

 

[24] Boron-Mediated Activation of Carbon Dioxide

S. Bontemps*

Coord. Chem. Rev. 2016, 308, Part 2, 117-130. Abstract

 

 

[23] Iron-Catalyzed C–H Borylation of Arenes

T. Dombray, C. G. Werncke, S. Jiang, M. Grellier, L. Vendier, S. Bontemps,* J.-B. Sortais,* S. Sabo-Etienne,* and C. Darcel*

J. Am. Chem. Soc. 2015, 137, 4062–4065

 

 

[22] Two-Coordinate Iron(I) Complex [Fe{N(SiMe3)2}2]−: Synthesis, Properties, and Redox Activity

C. G. Werncke, P. C. Bunting, C. Duhayon, J. R. Long, S. Bontemps,* S. Sabo-Etienne*

Angew. Chem. Int. Ed. 2015, 54, 245-248. Abstract

 

 

[21] Iron-Catalyzed Reduction of CO₂ into Methylene: Formation of C–N, C–O, and C–C Bonds

G. Jin, C. G. Werncke, Y. Escudié, S. Sabo-Etienne,* S. Bontemps*

J. Am. Chem. Soc. 2015, 137, 9563–9566. Abstract

 

 

[20] Three bonding modes of bis(2-picolyl)phenylphosphine at iron: isolation of a dinuclear iron complex featuring dearomatized pyridine moieties

G. Jin, L. Vendier, Y. Coppel, S Sabo-Etienne,* S. Bontemps*

Dalton Trans. 2015, 44, 7500-7505. Abstract

 

 

[19] Ruthenium-Catalyzed Reduction of Carbon Dioxide to Formaldehyde

S. Bontemps,* L. Vendier, S. Sabo-Etienne,*

J. Am. Chem. Soc. 2014, 136, 4419–4425. Abstract

 

[18] Trapping Formaldehyde in the Homogeneous Catalytic Reduction of Carbon Dioxide

S. Bontemps,* S. Sabo-Etienne*

Angew. Chem. Int. Ed. 2013, 52, 10253-10255. Hot Paper. Abstract

 

 

 

[17] Borane-Mediated Carbon Dioxide Reduction at Ruthenium: Formation of C1 and C2 Compounds

S. Bontemps, L. Vendier and S. Sabo-Etienne

Angew. Chem. Int. Ed. 2012, 51, 1671-1674.Abstract

 

 

[16] Comparative Reactivity of Zr– and Pd–Alkyl Complexes with Carbon Dioxide

K.-C. Lau, B. J. Petro, S. Bontemps, R. F. Jordan

Organometallics 2013, 32, 6895-6898. Abstract

 

 

[15] Phosphino-Boryl-Naphthalenes: Geometrically Enforced, Yet Lewis Acid Responsive P→B Interactions

 S. Bontemps, M. Devillard, S. Mallet-Ladeira, G. Bouhadir, K. Miqueu, D. Bourissou

 Inorg. Chem. 2013, 52, 4714-4720. Abstract

 

 

[14] Palladium-Catalyzed Aryl Iodide Carbonylation as a Route to Imidazoline Synthesis: Design of a Five-Component Coupling Reaction

 S. Bontemps, J. S. Quesnel, K. Worrall, B. A. Arndtsen

 Angew. Chem. Int. Ed. 2011, 50, 8948-8951. Abstract

 

 

[13] A Palladium-Catalyzed Multicomponent Synthesis of Imidazolinium Salts and Imidazolines from Imines, Acid Chlorides and Carbon Monoxide

K.Worrall, B. Xu, S. Bontemps, B. A. Arndtsen

J. Org. Chem. 2011, 76, 170-180. Abstract

 

 

[12] A 1,1’-ferrocenyl phosphine-borane : synthesis, structure and evaluation in Rh-catalyzed hydroformylation

 M. W. P. Bebbington, S. Bontemps, G. Bouhadir, M. J. Hanton, R. P. Tooze, H. van Rensburg, D. Bourissou

 New J. Chem. 2010, 34, 1556-1559. Abstract

 

 

[11] Copper(I) Complexes derived from Mono- and Diphosphino-Boranes : Cu→B Interactions Supported by Arene Coordination

 M. Sircoglou, S. Bontemps, M. Mercy, K. Miqueu, S. Ladeira, N. Saffon, L. Maron, G. Bouhadir, D. Bourissou

 Inorg. Chem. 2009 ,49, 3983-3990. Abstract

 

 

[10] Bridging M-Cl Bonds with Ambiphilic Phosphine–Borane Ligands

 S. Bontemps, G. Bouhadir, D. Apperley, P. W. Dyer, K. Miqueu, D. Bourissou

 Chem. Asian J. 2009, 4, 428-435. Abstract

 

 

[9] Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl and Au+) Derived from a Triphosphine–Borane

 M. Sircoglou, S. Bontemps, G. Bouhadir, N. Saffon, K. Miqueu, W. Gu, M. Mercy, C-H. Chen, B. Foxman, L. Maron, O. Ozerov, D. Bourissou

 J. Am. Chem. Soc. 2008, 130, 16729-16738. Abstract

 

 

[8] Base-Free Phosphine−Sulfonate Nickel Benzyl Complexes

 X. Zhou, S. Bontemps, R. F. Jordan

 Organometallics 2008, 27, 4821-4824. Abstract

 

 

[7] Metallaboratranes Derived from a Triphosphanyl-Borane : Intrinsic C3 Symmetry Supported by a Z-Type Ligand

 S. Bontemps, G. Bouhadir, W. Gu, M. Mercy, C-H. Chen, B. M. Foxman, L. Maron, O. Ozerov, D. Bourissou

 Angew. Chem. Int. Ed. 2008, 47, 1481-1484. Abstract

 

 

[6] Ambiphilic Diphosphine-Borane Ligands: Metal→Borane Interactions within Isoelectronic Complexes of Rhodium, Platinum and Palladium

 S. Bontemps, M. Sircoglou, G. Bouhadir, H. Puschmann, J. A. K. Howard, P. Dyer, K. Miqueu, D. Bourissou

 Chem. Eur. J. 2008, 14, 731-740. Abstract

 

 

[5] Transition-Metal Complexes Featuring Z-Type Ligands: Agreement or Discrepancy between Geometry and dn Configuration?

 M. Sircoglou, S. Bontemps, M. Mercy, N. Saffon, M. Takahashi, G. Bouhadir, L. Maron, D. Bourissou

 Angew. Chem. Int. Ed. 2007, 46, 8583-8586. Abstract

 

 

[4] P→B interaction within di- and tri-phosphineboranes

 S. Bontemps, G. Bouhadir, P. W. Dyer, K. Miqueu, D. Bourissou

 Inorg. Chem. 2007, 46, 5149-5149. Abstract

 

 

[3] Photoisomerizable Heterodienes derived from a Phosphine–Borane

 M. W. P. Bebbington, S. Bontemps, G. Bouhadir, D. Bourissou

 Angew. Chem. Int. Ed. 2007, 46, 3333-3336. Abstract

 

 

[2] On the Versatile and Unusual Coordination Behavior of Ambiphilic Ligands o-R2P(Ph)BR’2

 S. Bontemps, G. Bouhadir, K. Miqueu, D. Bourissou

 J. Am. Chem. Soc. 2006, 128, 12056-12057. Abstract

 

 

[1] Rhodium(I) Complexes of a PBP Ambiphilic Ligand : Evidence for a Metal→Borane Interaction

 S. Bontemps, H. Gornitzka, G. Bouhadir, K. Miqueu, D. Bourissou

 Angew. Chem. Int. Ed. 2006, 45, 1611-1614. Abstract